Scorpia was the warrior queen of Scorpioni people, race of warriors mutant half scorpions, his kingdom was at war with the mighty God "Shatalak" (creator of Scorpioni people) and King of the enemy who came from the fifth dimension to defeat the "Scorpion King" father of Scorpia who had died, his kingdom was taken by Shatalak who wanted to dominate all Etheria, Hordak and his troops under the command of captain Adora fought a battle with Shatalak who defeated God, destroying the gate of the fifth dimension completely losing his powers and sent to prison in the world of the horde.

The Scorpioni kingdom became a dark desert leaving the ruin of his castle where Scorpia lives in next to Crimson Waste, she surrenders to the world of the horde as a thank you, a part of the team as troop lieutenant.

At this place she owns slaves, which suggest that she is a powerful figure on Etheria. with your castle scorpion. Within the home can be seen a throne, suggesting Scorpia has some kind of rule over a new region of Etheria.

Scorpia and Catra possess a fierce rivalry between them, only working together as a last resort. She possesses claw-like pincers instead of hands and a powerful tail which she can employ to capture members of the Rebellion. Her tail is at times a disadvantage to her as She-Ra uses it several times to hurl her out of the way. She is not the most intelligent member of the Horde and is easily fooled, which is evidenced on several occasions, most notably when she allows Bow to enter the secret factory of the Horde believing him to be a handsome inspector.